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Creators/Authors contains: "Benz, Lauren"

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  1. ; ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract Low‐valent metal–organic frameworks (LVMOFs) and related materials have gained interest due to their potential applications in heterogeneous catalysis. However, of the few LVMOFs that have been reported, none have shown catalytic activity. Herein, a low‐valent metal‐organic material constructed from phosphine linkers and IrInodes is reported. This material is effectively a crystalline, insoluble analogue of Vaska's complex. As such, the material reversibly binds O2and catalyzes the reductive formation of enamines from amides. 
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